Copper(I)-Catalyzed Efficient and Stereoselective Synthesis of (E)-Vinyl Selenides and Tellurides by the Reaction of Potassium Vinyltrifluoroborates with Diphenyl Dichalcogenides
A mild, stereoselective, and effective strategy has been developed for the synthesis of (E)-vinyl selenides and (E)-vinyl tellurides by reaction of potassium vinyltrifluoroborates with the respective dichalcogenides using a copper salt as catalyst.
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Published in | Organometallics Vol. 27; no. 15; pp. 4009 - 4012 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
WASHINGTON
American Chemical Society
11.08.2008
Amer Chemical Soc |
Subjects | |
Online Access | Get full text |
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Summary: | A mild, stereoselective, and effective strategy has been developed for the synthesis of (E)-vinyl selenides and (E)-vinyl tellurides by reaction of potassium vinyltrifluoroborates with the respective dichalcogenides using a copper salt as catalyst. |
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Bibliography: | Text and figures giving experimental details and characterization data (1H NMR, 13C NMR, mass analysis, and elemental analysis) for all new compounds listed in Tables and . This material is available free of charge via the Internet at http://pubs.acs.org. ark:/67375/TPS-T0GDFK2X-Z istex:98610EB61AE5C20202AC2F7B345FFAB69BC5E76D |
ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om800052y |