Preparation and Structural Characterization of 1,4-Digerma-2-buten-1,4-diylplatinum(II) Complexes and Their Reactions with Alkynes, Carbon Monoxide, and Isocyanides

• Published in: Organometallics Vol. 24; no. 20; pp. 4734 - 4741
• Main Authors: Mochida, Kunio, Karube, Hironori, Nanjo, Masato, Nakadaira, Yasuhiro
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 26.09.2005; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; Physical Sciences; Science & Technology; DOUBLE SILYLATION; INSERTION; PLATINUM(II); SILICON; REACTIVITY; BOND ACTIVATION; REDUCTIVE ELIMINATION; GE; BRIDGING DISILENE; C-SI
• ISSN: 0276-7333; 1520-6041
• DOI: 10.1021/om058021v

1,4-Digerma-2-buten-1,4-diylplatinum(II) complexes were prepared by treatment of a (η-ethylene)(triphenylphosphine)platinum(0) complex with (Z)-α,β-bis(dialkylgermyl)styrenes, and their structures were determined by spectroscopic analysis coupled with X-ray diffraction methods. Thermolysis of 1,4-digerma-2-buten-1,4-diylplatinum(II) complexes afforded linear and cyclic trigermanes and a dinuclear platinum complex. The 1,4-digerma-2-buten-1,4-diylplatinum(II) complexes reacted with alkynes to give the corresponding insertion products, cyclic germyl(germylvinyl)platinum(II) species, whose structures have been determined by spectroscopic analysis. The cyclic germyl(germylvinyl)platinum(II) complexes were found to easily liberate 1,4-digermacyclohexa-2,5-dienes and a platinum(0) complex. The reactions of 1,4-digerma-2-buten-1,4-diylplatinum(II) complexes with carbon monoxide and isocyanides afforded the corresponding platinum complexes containing one carbon monoxide and one isocyanide ligand, respectively.