Preparation of Bis(trifluoromethyl) Compounds via Functionalization of 1,1,1,3,3,5,5,5-Octafluoropentane

The hydrochlorofluorocarbon CF3CH2CCl2CH2CF3 (3) was prepared from the hydrofluorocarbon CF3CH2CF2CH2CF3, by a selective Cl−F exchange reaction using AlCl3. Compound 3 was derivatized further to provide novel fluorinated intermediates including CF3CHCCHCF3, CF3CH2C(O)CH2CF3, and CF3CH2CH(OH)CH2CF3...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 62; no. 19; pp. 6466 - 6468
Main Author Van Der Puy, Michael
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.09.1997
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
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Summary:The hydrochlorofluorocarbon CF3CH2CCl2CH2CF3 (3) was prepared from the hydrofluorocarbon CF3CH2CF2CH2CF3, by a selective Cl−F exchange reaction using AlCl3. Compound 3 was derivatized further to provide novel fluorinated intermediates including CF3CHCCHCF3, CF3CH2C(O)CH2CF3, and CF3CH2CH(OH)CH2CF3.
Bibliography:Abstract published in Advance ACS Abstracts, August 15, 1997.
ark:/67375/TPS-DPG3H12V-S
istex:DA86A2F2654296A0A97061D9AE9D0247C7E7E41D
ISSN:0022-3263
1520-6904
DOI:10.1021/jo970655r