Dynamics–Entropy Relationship in Metallic Glasses

• Published in: The journal of physical chemistry letters Vol. 15; no. 3; pp. 811 - 816
• Main Authors: Cao, Lin-Li, Wang, Yun-Jiang
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 25.01.2024
• Subjects: Physical Insights into Materials and Molecular Properties
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.3c03530

Establishing a robust quantitative correlation between thermodynamics and dynamics in amorphous matter remains a significant challenge in condensed matter physics. Although the classical Adam–Gibbs relationship represents a pivotal step in this direction and the correlation between relaxation time and configurational entropy has been partially verified in simple liquids, this quantitative link has yet to be tested in realistic glass-forming systems where complex many-body interactions are present. Here we conduct free energy samplings and lattice dynamics analysis to distinguish vibrational entropy from configurational entropy in a realistic Cu–Zr model of a metallic glass. Our calculations unveil a power-law relationship (with a substantial exponent of ∼3) between the logarithmic relaxation time and configurational entropy, surpassing the linear prediction of the original Adam–Gibbs relationship. This nonlinear entropy driven relaxation time variation likely originates from anisotropic nature of atomic many-body interactions, suggesting that factors beyond thermodynamics contribute to the glass transition phenomenon.