Chemical Kinetic Approach To The Mechanism Of Coupled Transport Of Cu(II) Ions Through Bulk Liquid Membranes

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 103; no. 11; pp. 1553 - 1559
• Main Authors: Szpakowska, M, B.Nagy, O
• Format: Journal Article
• Language: English
• Published: American Chemical Society 18.03.1999
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/jp982779t

Transport of copper(II) ions through bulk liquid membranes is studied in various experimental conditions. The results obtained are analyzed by using the concepts and methods of chemical kinetics. This approach allowed kinetic equations to be established which are sufficiently general to account for a large variety of transport kinetics (steady or nonsteady state, first or zeroth order, diffusion or reaction controlled, reversible or irreversible), to identify clearly the rate-determining steps, and to propose a detailed mechanism at the molecular level. The important role played by the interfaces is also demonstrated.