Highly Stable Chiral (A)6–B Supramolecular Copolymers: A Multivalency-Based Self-Assembly Process
A novel type of chiral layered supramolecular copolymer with high molecular weight has been assembled from a hydrogen bonded C 6-symmetric zinc porphyrin hexamer and chiral C 3-symmetric pyridine hexadentate linkers driven by multivalent zinc porphyrin–pyridine coordination. UV–vis, circular dichroi...
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Published in | Journal of the American Chemical Society Vol. 133; no. 29; pp. 11124 - 11127 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
27.07.2011
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Subjects | |
Online Access | Get full text |
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Summary: | A novel type of chiral layered supramolecular copolymer with high molecular weight has been assembled from a hydrogen bonded C 6-symmetric zinc porphyrin hexamer and chiral C 3-symmetric pyridine hexadentate linkers driven by multivalent zinc porphyrin–pyridine coordination. UV–vis, circular dichroism, and static light scattering experiments revealed that the formation of the layered supramolecular copolymers is at first dynamically controlled and then becomes thermodynamically controlled. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja205059z |