Resonant Inelastic X‑ray Scattering of Molybdenum Oxides and Sulfides

Molybdenum oxides and sulfides were studied using resonant inelastic X-ray scattering (RIXS). The 2p3/23d Mo RIXS planes show a rich structure with considerably more spectral information than in conventional X-ray absorption near edge structure (XANES) spectroscopy. The spectra were simulated using...

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Published inJournal of physical chemistry. C Vol. 119; no. 5; pp. 2419 - 2426
Main Authors Thomas, Rowena, Kas, Josh, Glatzel, Pieter, Al Samarai, Mustafa, de Groot, Frank M. F, Alonso Mori, Roberto, Kavčič, Matjaž, Zitnik, Matjaz, Bucar, Klemen, Rehr, John J, Tromp, Moniek
Format Journal Article
LanguageEnglish
Published American Chemical Society 05.02.2015
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Summary:Molybdenum oxides and sulfides were studied using resonant inelastic X-ray scattering (RIXS). The 2p3/23d Mo RIXS planes show a rich structure with considerably more spectral information than in conventional X-ray absorption near edge structure (XANES) spectroscopy. The spectra were simulated using FEFF9 giving generally good agreement and detailed electronic information can be derived. The reference materials serve as a starting point for detailed electronic and geometric investigations of a broad range of compounds. In particular, this can provide insights in the properties and performance of unknown and changing materials like those in catalysis.
ISSN:1932-7447
1932-7455
DOI:10.1021/jp509376q