Design and Scalable Synthesis of New Chiral Selectors. Part 2: Chiral Ionic Liquids Derived from Diaminocyclohexane and Histidine

We disclose the conception and synthesis of new chiral selectors useful for enantioselective liquid–liquid extraction processes (ELLE). We report synthetic methods giving access to substantial amounts of the compounds, at least at the multigram scale. Two series are examined, i.e. ionic liquids base...

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Bibliographic Details
Published inOrganic process research & development Vol. 16; no. 2; pp. 277 - 285
Main Authors Zgonnik, Viacheslav, Gonella, Silvia, Mazières, Marie-Rose, Guillen, Frédéric, Coquerel, Gérard, Saffon, Nathalie, Plaquevent, Jean-Christophe
Format Journal Article
LanguageEnglish
Published American Chemical Society 17.02.2012
Subjects
Chemical Sciences
Organic chemistry
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Summary:We disclose the conception and synthesis of new chiral selectors useful for enantioselective liquid–liquid extraction processes (ELLE). We report synthetic methods giving access to substantial amounts of the compounds, at least at the multigram scale. Two series are examined, i.e. ionic liquids based on diaminocyclohexane (DACH) and histidine, respectively.
ISSN:1083-6160
1520-586X
DOI:10.1021/op200082a