Highly Regioselective Nucleophilic Carbon−Carbon Bond Formation on Furans and Thiophenes Initiated by Pummerer-Type Reaction

The reactions of (phenylsulfinyl)furans or -thiophenes with carbon nucleophiles in the presence of trifluoroacetic anhydride allowed the nucleophilic installation of carbon functional groups on the furan and thiophene nuclei with complete regioselectivity.

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Bibliographic Details
Published inOrganic letters Vol. 6; no. 21; pp. 3793 - 3796
Main Authors Akai, Shuji, Kawashita, Norihito, Satoh, Hideharu, Wada, Yasufumi, Kakiguchi, Keisuke, Kuriwaki, Ikumi, Kita, Yasuyuki
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 14.10.2004
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Summary:The reactions of (phenylsulfinyl)furans or -thiophenes with carbon nucleophiles in the presence of trifluoroacetic anhydride allowed the nucleophilic installation of carbon functional groups on the furan and thiophene nuclei with complete regioselectivity.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol0484310