Square-Planar Silver(I)-Containing Polymers Formed from π-Stacked Entities

The flexible ligand 4,6-bis(3‘-pyridylmethylsulfanyl)dibenzofuran (L) was synthesized in a three-step reaction sequence. This new ligand was complexed with both AgClO4 and AgNO3, in a 1:2 metal-to-ligand ratio. The isomorphous structures were one-dimensional coordination polymers each containing a r...

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Bibliographic Details
Published inCrystal growth & design Vol. 6; no. 4; pp. 833 - 835
Main Authors Hanton, Lyall R, Young, Aidan G
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 01.04.2006
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Multidisciplinary
Condensed matter: structure, mechanical and thermal properties
Crystallography
Exact sciences and technology
Materials Science
Materials Science, Multidisciplinary
Organic compounds
Organometalloidal and organometallic compounds
Physical Sciences
Physics
Science & Technology
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Technology
CHAIN
COORDINATION POLYMER
LIGANDS
DATABASE
CRYSTAL-STRUCTURE
COMPLEXES
SILVER(I)
GEOMETRY
Stacking sequence
Polychelate
Organometallic compounds
Silver complexes
Isomorphism
XRD
Nuclear magnetic resonance
Experimental study
Benzofurans
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Summary:The flexible ligand 4,6-bis(3‘-pyridylmethylsulfanyl)dibenzofuran (L) was synthesized in a three-step reaction sequence. This new ligand was complexed with both AgClO4 and AgNO3, in a 1:2 metal-to-ligand ratio. The isomorphous structures were one-dimensional coordination polymers each containing a rare square-planar Ag(I) connector. The X-ray structures showed numerous π interactions.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg0506267