Thermodynamic Properties of the Binary Mixtures of 1,2-Dichloroethane with Chlorobenzene and Bromobenzene from (298.15 to 313.15) K

Densities, viscosities, and refractive indices for the binary mixtures of 1,2-dichloroethane with chlorobenzene and bromobenzene have been determined from (298.15 to 313.15) K over the entire range of concentration at atmospheric pressure. Excess molar volumes have been calculated from the experimen...

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Bibliographic Details
Published inJournal of chemical and engineering data Vol. 55; no. 10; pp. 4541 - 4545
Main Authors Ni, Bangqing, Su, Liyan, Wang, Haijun, Qiu, Haigang
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 14.10.2010
Subjects
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
Viscosity
Binary mixture
Molar volume
Chlorocarbon
Optical properties
Refraction index
Bromocarbon
Excess parameter
Thermodynamic properties
Density
Rheological properties
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Summary:Densities, viscosities, and refractive indices for the binary mixtures of 1,2-dichloroethane with chlorobenzene and bromobenzene have been determined from (298.15 to 313.15) K over the entire range of concentration at atmospheric pressure. Excess molar volumes have been calculated from the experimental data and fitted to a Redlich−Kister polynomial function. The ability of the Prigogine−Flory−Patterson (PFP) theory to predict V m E at 303.15 K has been tested.
ISSN:0021-9568
1520-5134
DOI:10.1021/je100552a