Synthesis and Characterization of a Bisadduct of La@C82

A bisadduct of La@C82 has been synthesized in a good yield by a Bingel−Hirsch reaction. Its structure has been well-defined by X-ray crystallographic analysis. A pair of enantiomers of the adduct form a dimer in the single crystal.

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 128; no. 18; pp. 5990 - 5991
Main Authors Feng, Lai, Tsuchiya, Takahiro, Wakahara, Takatsugu, Nakahodo, Tsukasa, Piao, Qiuyue, Maeda, Yutaka, Akasaka, Takeshi, Kato, Tatsuhisa, Yoza, Kenji, Horn, Ernst, Mizorogi, Naomi, Nagase, Shigeru
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 10.05.2006
Subjects
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Miscellaneous
Preparations and properties
Encapsulation
Fullerene compounds
Molecular structure
EPR spectrometry
Differential impulse voltamperometry
HPLC chromatography
Metallofullerenes
Inorganic synthesis
Electrochemical properties
Electronic structure
Lanthanum
Redox potential
Chemical reactivity
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Summary:A bisadduct of La@C82 has been synthesized in a good yield by a Bingel−Hirsch reaction. Its structure has been well-defined by X-ray crystallographic analysis. A pair of enantiomers of the adduct form a dimer in the single crystal.
Bibliography:ark:/67375/TPS-MTM0F2M3-P
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ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja058390i