Thermal Offset Viscosities of Liquid H2O, D2O, and T2O

• Published in: The journal of physical chemistry. B Vol. 103; no. 11; pp. 1991 - 1994
• Main Authors: Cho, C. H, Urquidi, J, Singh, S, Robinson, G. Wilse
• Format: Journal Article
• Language: English
• Published: American Chemical Society 18.03.1999
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp9842953

As suggested in a previous study under the title “Simple Relationship Between the Properties of Isotopic Water”, viscosity results verify the fact that the structural properties of liquid H2O and D2O are nearly identical once a zero-point-energy-induced thermal offset effect is taken into account. This means that the viscosities of these two isotopic forms must be compared at different temperatures, rather than at the same temperature. Only in this way can the expected (M D 2 O/M H 2 O)1/2 viscosity ratio be retrieved. Application of this most simple idea, with no additional parameter adjustment, to H2O viscosity data, or equivalently to any of the existing empirical viscosity equations for H2O, leads to D2O viscosities having better than 1% accuracy over a wide temperature range. This isotopic correlation concept has also been used here to predict viscosities of liquid T2O, no viscosity data apparently being available for this substance.