Inkjet Printability Assessment of Weakly Viscoelastic Fluid: A Semidilute Polyvinylpyrrolidone Solution Ink Case Study

• Published in: Langmuir Vol. 37; no. 28; pp. 8557 - 8568
• Main Authors: Suly, Pavol, Sevcik, Jakub, Dmonte, David J, Urbanek, Pavel, Kuritka, Ivo
• Format: Journal Article
• Language: English
• Published: American Chemical Society 20.07.2021
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.1c01010

Here, we present an integrated approach to the weakly viscoelastic fluid printability assessment by using global dimensionless criteria (DC). The problem was studied on a model semidiluted polyvinylpyrrolidone water-based ink. For the study purpose, the ink composition was kept as simple as possible. First, the solution density, viscosity, and surface tension were determined. Obtained data were used for testing limitations of DC printability diagrams already available for Newtonian fluids. A replotted version of the original Kim and Baek’s map was developed emphasizing the importance of surface tension in the drop formation process. Another set of DC (e.g., Ec and De) was also used for a real evaluation of the viscoelasticity effect on both jetting conditions and drop formation. The polymer relaxation time as a crucial parameter for viscoelasticity was shown to be calculated using the Kuhn segment length rather than from Zimm and Rouse theories for diluted polymer systems. Then, a two-dimensional diagram using four DC (Oh and De with Ec and El as parameters) is proposed based on the famous McKinley’s work. The diagram describes the interplay of possible forces responsible for filament thinning and breakup processes. Obtained results were supported by further experiments involving drop ejection and formation, determination of critical polymer concentration, and others. The proposed diagram promises a useful initial step in further investigations of viscoelasticity of polymer compounds by inkjet printing.