Densities of Carbon Dioxide + Hydrogen Sulfide Mixtures from 220 K to 450 K at Pressures up to 25 MPa
This paper reports ∼850 pVT measurements at temperatures between 220 K and 450 K at pressures up to 25 MPa for four gravimetrically prepared CO2 (1) + H2S (2) mixtures with x 1 = 0.5011, 0.7067, 0.9045, and 0.9393. The measurements utilized a Burnett isochoric technique designed to provide both vapo...
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Published in | Journal of chemical and engineering data Vol. 46; no. 5; pp. 1309 - 1318 |
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Main Authors | , , , , , |
Format | Journal Article Conference Proceeding |
Language | English |
Published |
Washington, DC
American Chemical Society
13.09.2001
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Subjects | |
Online Access | Get full text |
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Summary: | This paper reports ∼850 pVT measurements at temperatures between 220 K and 450 K at pressures up to 25 MPa for four gravimetrically prepared CO2 (1) + H2S (2) mixtures with x 1 = 0.5011, 0.7067, 0.9045, and 0.9393. The measurements utilized a Burnett isochoric technique designed to provide both vapor and liquid densities. A detailed error analysis indicates that the densities are accurate to better than 0.08% and 0.3% for the vapor and liquid phases, respectively. Mixture second and third virial coefficients derived from the measurements and correlations to represent them and 52 derived vapor−liquid saturation boundary conditions also are included. |
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Bibliography: | istex:110CBF3812F9BF03314D0FFB2968F1E0C6F68525 ark:/67375/TPS-FV8XJBFR-3 |
ISSN: | 0021-9568 1520-5134 |
DOI: | 10.1021/je000182c |