Dehydrogenative Cross-Coupling of α,β-Unsaturated Compounds with Unactivated Olefins via Co(III) Catalysis

• Published in: Organic letters Vol. 25; no. 34; pp. 6284 - 6289
• Main Authors: Logeswaran, Ravichandran, Jeganmohan, Masilamani
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 01.09.2023; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; OXIDATIVE OLEFINATION; FUNCTIONALIZATION; ACTIVATION; BONDS; C-H OLEFINATION; ELECTRON-DEFICIENT ALKENES; EFFICIENT; ACCESS; ALKENYLATION; AMIDES

An oxidative cross-coupling of α,β-unsaturated compounds with unactivated alkenes via cobalt-catalyzed vinylic C–H activation has been developed. The present catalytic reaction was examined with various differently functionalized unsaturated compounds and unactivated olefins. In these reactions, hig...