Dehydrogenative Cross-Coupling of α,β-Unsaturated Compounds with Unactivated Olefins via Co(III) Catalysis
An oxidative cross-coupling of α,β-unsaturated compounds with unactivated alkenes via cobalt-catalyzed vinylic C–H activation has been developed. The present catalytic reaction was examined with various differently functionalized unsaturated compounds and unactivated olefins. In these reactions, hig...
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| Published in | Organic letters Vol. 25; no. 34; pp. 6284 - 6289 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
01.09.2023
Amer Chemical Soc |
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| Abstract | An oxidative cross-coupling of α,β-unsaturated compounds with unactivated alkenes via cobalt-catalyzed vinylic C–H activation has been developed. The present catalytic reaction was examined with various differently functionalized unsaturated compounds and unactivated olefins. In these reactions, highly valuable amide functionalized butadienes and indenones were prepared in good to excellent yields. A possible reaction mechanism is proposed involving directed olefinic C–H activation through a base-assisted deprotonation pathway. |
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| AbstractList | An oxidative cross-coupling of α,β-unsaturated compounds with unactivated alkenes via cobalt-catalyzed vinylic C–H activation has been developed. The present catalytic reaction was examined with various differently functionalized unsaturated compounds and unactivated olefins. In these reactions, highly valuable amide functionalized butadienes and indenones were prepared in good to excellent yields. A possible reaction mechanism is proposed involving directed olefinic C–H activation through a base-assisted deprotonation pathway. An oxidative cross-coupling of & alpha;,& beta;-unsaturatedcompoundswith unactivated alkenes via cobalt-catalyzed vinylic C-Hactivation has been developed. The present catalytic reaction wasexamined with various differently functionalized unsaturated compoundsand unactivated olefins. In these reactions, highly valuable amidefunctionalized butadienes and indenones were prepared in good to excellentyields. A possible reaction mechanism is proposed involving directedolefinic C-H activation through a base-assisted deprotonationpathway. |
| Author | Logeswaran, Ravichandran Jeganmohan, Masilamani |
| AuthorAffiliation | Department of Chemistry |
| AuthorAffiliation_xml | – name: Department of Chemistry |
| Author_xml | – sequence: 1 givenname: Ravichandran surname: Logeswaran fullname: Logeswaran, Ravichandran – sequence: 2 givenname: Masilamani orcidid: 0000-0002-7835-3928 surname: Jeganmohan fullname: Jeganmohan, Masilamani email: mjeganmohan@iitm.ac.in |
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| Keywords | OXIDATIVE OLEFINATION FUNCTIONALIZATION ACTIVATION BONDS C-H OLEFINATION ELECTRON-DEFICIENT ALKENES EFFICIENT ACCESS ALKENYLATION AMIDES |
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| Snippet | An oxidative cross-coupling of α,β-unsaturated compounds with unactivated alkenes via cobalt-catalyzed vinylic C–H activation has been developed. The present... An oxidative cross-coupling of & alpha;,& beta;-unsaturatedcompoundswith unactivated alkenes via cobalt-catalyzed vinylic C-Hactivation has been developed. The... |
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| Title | Dehydrogenative Cross-Coupling of α,β-Unsaturated Compounds with Unactivated Olefins via Co(III) Catalysis |
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