Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-media...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 89; no. 21; pp. 16055 - 16059
Main Authors Kitcatt, David M., Pogacar, Eva, Mi, Le, Nicolle, Simon, Lee, Ai-Lan
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 01.11.2024
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Summary:Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.
Bibliography:ObjectType-Article-1
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content type line 23
ISSN:0022-3263
1520-6904
1520-6904
DOI:10.1021/acs.joc.4c02163