Stereochemistry and mechanism of the reverse ene reaction of cis-2-alkyl-1-alkenylcyclobutanes. Stereoelectronic control in a system showing marginal energetic benefit of concert

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 113; no. 12; pp. 4607 - 4621
Main Authors Getty, Stephen J, Berson, Jerome A
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.06.1991
Subjects
Chemical reactivity
Chemistry
Exact sciences and technology
Organic chemistry
Reactivity and mechanisms
Deuterium
Pyrolysis
Ether
Reverse reaction
Hydrogen Isotopes
Kinetic isotope effect
Simulation
Ene reaction
Arrhenius equation
Reaction mechanism
Stereospecificity
Stereoelectronic control
Gas phase
Rate constant
Thermodynamic properties
Monocyclic compound
Ethylenic compound
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Bibliography:istex:1210FB32E33C9C71D7F25DF17755C88C529E9376
ark:/67375/TPS-KV643GTC-S
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00012a033