Crystal structures of .alpha.-[CoIIW12O40]6- and its heteropoly blue 2e reduction product, .alpha.-[CoIIW12O40]8-. Structural, electronic, and chemical consequences of electron delocalization in a multiatom mixed-valence system

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 113; no. 15; pp. 5658 - 5663
Main Authors Casan-Pastor, Nieves, Gomez-Romero, Pedro, Jameson, Geoffrey B, Baker, Louis C. W
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.07.1991
Subjects
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Cobalt II Tungsten Complexes
Molecular structure
Complex cluster
Anionic complex
Transition metal Complexes
Experimental study
X ray diffraction
Potassium Compounds
Oxo complex
Inorganic compound
Chemical reduction
Mu complex
Heteronuclear complex
Polynuclear complex
Hydrates
Crystalline structure
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Bibliography:istex:3C4F9D10F065BCBAF771E47C434868BD94581322
ark:/67375/TPS-QZ8N0P17-8
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00015a020