Enantiopure C 1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation

Enantiopure C 1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 134; no. 10; pp. 4561 - 4564
Main Authors Monfette, Sebastien, Turner, Zoë R, Semproni, Scott P, Chirik, Paul J
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 14.03.2012
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
DICHLORIDE
ELECTRONIC-STRUCTURES
ALPHA-OLEFINS
CATALYSIS
IRON COMPLEXES
DINITROGEN
LIGAND
CO
ETHYLENE POLYMERIZATION
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Summary:Enantiopure C 1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja300503k