Ligand Exchange in Mixed Organocuprate(I) π‑Complexes
π-Complexes of mixed organocuprate(I) reagents with α,β-unsaturated carbonyl compounds can undergo ligand exchange to give the corresponding homocuprate–olefin π-complexes. The mechanism of this metathesis, which has profound implications for synthetic applications, involves a second-order reaction...
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Published in | Organometallics Vol. 31; no. 22; pp. 7809 - 7811 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
26.11.2012
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Online Access | Get full text |
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Summary: | π-Complexes of mixed organocuprate(I) reagents with α,β-unsaturated carbonyl compounds can undergo ligand exchange to give the corresponding homocuprate–olefin π-complexes. The mechanism of this metathesis, which has profound implications for synthetic applications, involves a second-order reaction of the mixed cuprate with the mixed cuprate–olefin π-complex. |
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ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om3006646 |