ZnO with Different Morphologies Synthesized by Solvothermal Methods for Enhanced Photocatalytic Activity

• Published in: Chemistry of materials Vol. 21; no. 13; pp. 2875 - 2885
• Main Authors: Xu, Linping, Hu, Yan-Ling, Pelligra, Candice, Chen, Chun-Hu, Jin, Lei, Huang, Hui, Sithambaram, Shanthakumar, Aindow, Mark, Joesten, Raymond, Suib, Steven L
• Format: Journal Article
• Language: English
• Published: American Chemical Society 14.07.2009
• Subjects: Characterization of Materials; Inorganic Solids and Ceramics; Microstructure
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm900608d

ZnO materials with a range of different morphologies have been synthesized via a simple solvothermal method with different solvents. Zinc acetylacetonate was used as the zinc source in such solvothermal syntheses for the first time. XRD data showed that single-phase ZnO with the wurtzite crystal structure was obtained for all the solvents used. FE-SEM imaging showed that ZnO with cauliflower-like, truncated hexagonal conical, tubular and rodlike, hourglass-like, nanorods, and spherical shapes were produced when THF, decane, water, toluene, ethanol, and acetone were used as the solvent, respectively. The TEM data showed that the crystalline ZnO had different growth habits in the different solvents. The optical properties of the as-prepared ZnO materials were investigated by UV−vis absorption and room temperature photoluminescence. Photodegradation of phenol was used as a model reaction to test the photocatalytic activity of the ZnO samples. ZnO samples with different morphologies and crystal growth habits exhibited different activities to phenol degradation. The ZnO material prepared using THF as the solvent showed a nine-times enhancement of the kinetic rate constants over commercial ZnO (0.1496 min−1 vs 0.0182 min−1). The influence of the solvents on the morphology of ZnO samples and the effect of the morphologies on the photocatalytic activity are discussed.