Pd-Catalyzed Oxidative Dehydrogenative Cross Coupling of Cage B–H/B–H Bonds at Room Temperature: Synthesis of Bis(o‑carborane)s
Efficient Pd-catalyzed oxidative dehydrogenative cross coupling of B–H/B–H bonds of two pyridyl o-carboranes has been developed, leading to the preparation of B(3)–B(6′) heterocoupled and B(3)–B(6′) homocoupled biscarboranes with a broad substrate scope at room temperature.
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| Published in | Inorganic chemistry Vol. 61; no. 35; pp. 13756 - 13767 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
05.09.2022
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| Online Access | Get full text |
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| Summary: | Efficient Pd-catalyzed oxidative dehydrogenative cross coupling of B–H/B–H bonds of two pyridyl o-carboranes has been developed, leading to the preparation of B(3)–B(6′) heterocoupled and B(3)–B(6′) homocoupled biscarboranes with a broad substrate scope at room temperature. |
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| Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 0020-1669 1520-510X |
| DOI: | 10.1021/acs.inorgchem.2c01360 |