Mixed-Valent Stellated Cuboctahedral Cu(2,4-Imdb)-MOF for Trace Water Detection
Developing an economical and robust sensor using an earth-abundant metal-based metal–organic framework (MOF) to detect trace water content rapidly is crucial for laboratories and chemical industries. Herein, a mixed-valent chiral [{Cu+Cu3 2+(2,4-Imdb)3(H2O)3}·Cl]∞ MOF manifests atypical quantitative...
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Published in | Inorganic chemistry Vol. 61; no. 46; pp. 18340 - 18345 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
21.11.2022
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Online Access | Get full text |
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Summary: | Developing an economical and robust sensor using an earth-abundant metal-based metal–organic framework (MOF) to detect trace water content rapidly is crucial for laboratories and chemical industries. Herein, a mixed-valent chiral [{Cu+Cu3 2+(2,4-Imdb)3(H2O)3}·Cl]∞ MOF manifests atypical quantitative detection of a trace amount of water [0.016% (v/v)] in organic solvents. Single-crystal X-ray diffraction and time-correlated single-photon counting supported the mechanism for turn-on fluorescence. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0020-1669 1520-510X |
DOI: | 10.1021/acs.inorgchem.2c02791 |