Z‑Scheme Photocatalytic CO2 Reduction on a Heterostructure of Oxygen-Defective ZnO/Reduced Graphene Oxide/UiO-66-NH2 under Visible Light

• Published in: ACS applied materials & interfaces Vol. 11; no. 1; pp. 550 - 562
• Main Authors: Meng, Jingchai, Chen, Qian, Lu, Jiaqian, Liu, Hong
• Format: Journal Article
• Language: English
• Published: American Chemical Society 09.01.2019
• Subjects: carbon dioxide; coordination polymers; electrons; energy conversion; formic acid; graphene; graphene oxide; lighting; methanol; photocatalysis; photocatalysts; remediation; semiconductors; zinc oxide; oxygen-defective; Z-scheme; photocatalytic; CO2 reduction; metal−organic framework
• ISSN: 1944-8244; 1944-8252; 1944-8252
• DOI: 10.1021/acsami.8b14282

The construction of a Z-scheme heterojunction is an effective way to isolate photogenerated electron–holes and enhance the activity of the semiconductor photocatalysts. However, the Z-scheme heterojunctions based on metal–organic frameworks were rarely reported. Herein, a novel oxygen-defective ZnO (O-ZnO)/reduced graphene oxide (rGO)/UiO-66-NH2 Z-scheme heterojunction has been prepared by a facile solvothermal route. The morphologies, structures, and photoelectric characteristics of the acquired materials were characterized in detail. The photocatalytic activity of the O-ZnO/rGO/UiO-66-NH2 heterostructure was assessed by photocatalytic CO2 reduction. The results indicated that the O-ZnO/rGO/UiO-66-NH2 heterostructure could efficiently reduce CO2 to CH3OH and HCOOH, and its activity was significantly superior to that of O-ZnO/UiO-66-NH2 and ZnO/rGO/UiO-66-NH2. Under illumination of visible light, the yield of CH3OH and HCOOH over the O-ZnO/rGO/UiO-66-NH2 heterostructure reached 34.83 and 6.41 μmol g–1 h–1, respectively. The high photoactivity of the O-ZnO/rGO/UiO-66-NH2 heterostructure should be caused by the effective spatial separation of photogenerated electrons and holes via a Z-scheme charge transfer. This research may well present an insight into the design and fabrication of novel Z-scheme photocatalytic systems for environmental remediation and energy conversion.