Catalytic asymmetric synthesis with trans-chelating chiral diphosphine ligand TRAP: rhodium-catalyzed asymmetric Michael addition of .alpha.-cyano carboxylates

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 114; no. 21; pp. 8295 - 8296
Main Authors Sawamura, Masaya, Hamashima, Hitoshi, Ito, Yoshihiko
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.10.1992
Subjects
Chemical reactivity
Chemistry
Exact sciences and technology
Organic chemistry
Reactivity and mechanisms
Michael addition
Rhodium Carbonyl Complexes
Enantioselectivity
Tertiary phosphine
Aliphatic compound
Organic ligand
Transition metal Carbonyl Complexes
Asymmetric catalysis
Metallocene
Hydrido complex
Iron Organic compounds
Platinoid Carbonyl Complexes
Asymmetric synthesis
Ditertiary phosphine
Carboxylate
Cyanoester
Enone
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More Information
Bibliography:ark:/67375/TPS-3TJ2RP94-B
istex:9FC2EE36063C61DA98C29C60E2EA0F3B427026E6
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00047a053