Role of the ligand in the formation of short vanadium-vanadium contacts. Preparation and crystal structure of monomeric {[(Ph2P)2CH]3V}[Li(THF)4](THF)2 and [PhNC(H)NPh]2V(TMEDA) and dimeric {[PhNC(Me)O]2V}2(TMEDA) (TMEDA = N,N,N',N'-tetramethylethylenediamine)

• Published in: Inorganic chemistry Vol. 30; no. 9; pp. 2056 - 2061
• Main Authors: Edema, Jilles J. H, Meetsma, Auke, Van Bolhuis, Fre, Gambarotta, Sandro
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 01.05.1991
• Subjects: Chemistry; Condensed matter: structure, mechanical and thermal properties; Coordination compounds; Exact sciences and technology; Inorganic chemistry and origins of life; Inorganic compounds; Metal complexes; Physics; Preparations and properties; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Molecular structure; Ion pair; Organic ligand; Transition metal Complexes; Experimental study; X ray diffraction; Diamine; Mu complex; Vanadium III Complexes; Ditertiary phosphine; Preparation; Dinuclear complex; Lithium Complexes; Alkali metal Complexes; Crystalline structure
• ISSN: 0020-1669; 1520-510X
• DOI: 10.1021/ic00009a022