Solvent effects on electron delocalization in paramagnetic organometallic complexes: solvent manipulation of the amount of 19-electron character in Co(CO)3L2 (L2 = a chelating phosphine)

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 114; no. 16; pp. 6418 - 6424
Main Authors Mao, Fei, Tyler, David R, Bruce, Mitchell R. M, Bruce, Alice E, Rieger, Anne L, Rieger, Philip H
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.07.1992
Subjects
Biological and medical sciences
Electronic structure
Fundamental and applied biological sciences. Psychology
Molecular biophysics
Structure in molecular biology
Solvent effect
Absorption
Phosphine
Chelating agent
Organometallic compound
Electron delocalization
EPR spectrum
Molecular adduct
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Bibliography:ark:/67375/TPS-9V5B7XHV-P
istex:2EE8D2042D69D85EEFDEE556B7ADF8580E40ADD7
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00042a019