Facial–Meridional Isomerization and Reductive Elimination in [(R2P‑o‑C6H4)2N]PtMe3 (R = Ph, iPr)
Treatment of PtMe3I in tetrahydrofuran with either in situ prepared [R-PNP]Li ([R-PNP]− = [(R2P-o-C6H4)2N]−; R = Ph, iPr) or H[R-PNP] in the presence of triethylamine at room temperature affords quantitatively fac-[R-PNP]PtMe3. Thermolysis of fac-[R-PNP]PtMe3 in benzene solutions generates mer-[R...
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Published in | Inorganic chemistry Vol. 60; no. 20; pp. 15118 - 15123 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
18.10.2021
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Online Access | Get full text |
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Summary: | Treatment of PtMe3I in tetrahydrofuran with either in situ prepared [R-PNP]Li ([R-PNP]− = [(R2P-o-C6H4)2N]−; R = Ph, iPr) or H[R-PNP] in the presence of triethylamine at room temperature affords quantitatively fac-[R-PNP]PtMe3. Thermolysis of fac-[R-PNP]PtMe3 in benzene solutions generates mer-[R-PNP]PtMe3 and ultimately [R-PNP]PtMe and ethane. Complexes mer-[R-PNP]PtMe3 represent the first meridional trialkylplatinum(IV) derivatives to date. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0020-1669 1520-510X |
DOI: | 10.1021/acs.inorgchem.1c02494 |