Discrete Hexa- and Binuclear Heterometallic Iodobismuthate(III) Complexes with Cu(I) and Ag(I)

The rare examples of discrete anionic halobismuthates­(III) with group 11 elements were obtained. Those are (3-MePyH)6[Bi4Cu2I20] (1) and (3,5-MePyC6)3[BiAgI7]2 (2) (3-MePyH = 3-methylpyridinium cation, 3,5-MePyC6=1,6-bis­(3,5-dimethylpyridinium)­hexane dication). Both complexes were isolated as pur...

Full description

Saved in:
Bibliographic Details
Published inInorganic chemistry Vol. 63; no. 40; pp. 18774 - 18780
Main Authors Shentseva, Irina A., Usoltsev, Andrey N., Korobeynikov, Nikita A., Sokolov, Maxim N., Adonin, Sergey A.
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 07.10.2024
Online AccessGet full text

Cover

More Information
Summary:The rare examples of discrete anionic halobismuthates­(III) with group 11 elements were obtained. Those are (3-MePyH)6[Bi4Cu2I20] (1) and (3,5-MePyC6)3[BiAgI7]2 (2) (3-MePyH = 3-methylpyridinium cation, 3,5-MePyC6=1,6-bis­(3,5-dimethylpyridinium)­hexane dication). Both complexes were isolated as pure phases; the optical band gaps for 1 and 2 are 1.75 and 2.23 eV, respectively.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
1520-510X
DOI:10.1021/acs.inorgchem.4c02792