N‑Acylimino‑λ3‑iodanes from the Metathesis of Iodosoarenes and Nitriles for the Photoinduced C–H Perfluoroacylamination of (Hetero)Arenes

An efficient and scalable synthesis of N-perfluoroacylimino-λ3-iodanes was achieved via an unprecedented metathesis between iodosoarenes and perfluoroalkanenitriles. The perfluoroacylamino groups of the iodanes could be introduced to aromatic and heteroaromatic rings using photoirradiation.

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Bibliographic Details
Published inOrganic letters Vol. 24; no. 26; pp. 4835 - 4839
Main Authors Kimura, Tomohiro, Hamada, Shohei, Furuta, Takumi, Takemoto, Yoshiji, Kobayashi, Yusuke
Format Journal Article
LanguageEnglish
Published American Chemical Society 08.07.2022
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Summary:An efficient and scalable synthesis of N-perfluoroacylimino-λ3-iodanes was achieved via an unprecedented metathesis between iodosoarenes and perfluoroalkanenitriles. The perfluoroacylamino groups of the iodanes could be introduced to aromatic and heteroaromatic rings using photoirradiation.
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ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.2c02054