High Voltage Magnesium-ion Battery Enabled by Nanocluster Mg3Bi2 Alloy Anode in Noncorrosive Electrolyte

• Published in: ACS nano Vol. 12; no. 6; pp. 5856 - 5865
• Main Authors: Tan, Yi-Hong, Yao, Wei-Tang, Zhang, Tianwen, Ma, Tao, Lu, Lei-Lei, Zhou, Fei, Yao, Hong-Bin, Yu, Shu-Hong
• Format: Journal Article
• Language: English
• Published: American Chemical Society 26.06.2018
• Subjects: high voltage; nanoclusters; noncorrosive electrolyte; Mg3Bi2 alloy; magnesium-ion battery
• ISSN: 1936-0851; 1936-086X; 1936-086X
• DOI: 10.1021/acsnano.8b01847

Currently, developing high voltage (beyond 2 V) rechargeable Mg-ion batteries still remains a great challenge owing to the limit of corrosive electrolyte and low compatibility of anode material. Here we report a facile one step solid state alloying route to synthesize nanoclustered Mg3Bi2 alloy as a high-performance anode to build up a 2 V Mg-ion battery using noncorrosive electrolyte. The fabricated nanoclustered Mg3Bi2 anode delivers a high reversible specific capacity (360 mAh g–1) with excellent stability (90.7% capacity retention over 200 cycles) and high Coulombic efficiency (average 98%) at 0.1 A g–1. The good performance is attributed to the stable nanostructures, which effectively accommodate the reversible Mg2+ ion insertion/deinsertion without losing electric contact among clusters. Significantly, the nanoclustered Mg3Bi2 anode can be coupled with high voltage cathode Prussian Blue to assemble a full cell using noncorrosive electrolyte, showing a stable cycling (88% capacity retention over 200 cycles at 0.2 A g–1) and good rate capability (103 mAh g–1 at 0.1 A g–1 and 58 mAh g–1 at 2 A g–1). The energy and power density of the as-fabricated full cell can reach up to 81 Wh kg–1 and 2850 W kg–1, respectively, which are both the highest values among the reported Mg-ion batteries using noncorrosive electrolytes. This study demonstrates a cost-effective route to fabricate stable and high voltage rechargeable Mg-ion battery potentially for grid-scale energy storage.