Praseodymium-Doped Ge20In5Sb10Se65 Films Based on Argon Plasma Cosputtering for Infrared-Luminescent Integrated Photonic Circuits

• Published in: ACS applied materials & interfaces Vol. 16; no. 4; pp. 5225 - 5233
• Main Authors: Starecki, Florent, Baillieul, Marion, Ghanawi, Taghrid, Hammouti, Abdelali, Lemaitre, Jonathan, Gutwirth, Jan, Benardais, Albane, Slang, Stanislav, Charrier, Joël, Bodiou, Loïc, Nemec, Petr, Nazabal, Virginie
• Format: Journal Article
• Language: English
• Published: American Chemical Society 31.01.2024
• Subjects: Surfaces, Interfaces, and Applications; rare earth; infrared; luminescence; amorphous chalcogenides; waveguides
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.3c14602

In this paper, we report on the infrared luminescence of amorphous praseodymium-doped Ge20In5Sb10Se65 waveguides, which can be used as infrared sources in photonic integrated circuits on silicon substrates. Amorphous chalcogenide thin films were deposited by radiofrequency magnetron cosputtering using an argon plasma whose deposition parameters were optimized for chalcogenide materials. The micropatterning as ridge waveguides of the chalcogenide cosputtered films was performed using photolithography and plasma-coupled reactive ion etching techniques. The influence of the rare earth concentration within those thin films on their optical properties and rare earth spectroscopic properties was investigated. Using an excitation wavelength of 1.55 μm, the mid-infrared luminescence of Pr3+ ions from 2.5 to 5.5 μm was clearly demonstrated for studied chalcogenide materials. A wide range of waveguide widths and doping ratios were tested, assessing the ability of the cosputtering technique to preserve the luminescence properties of the rare earth ions initially observed in the bulk glass through the thin-film deposition and patterning process.