Redox Reactions of Organic Molecules Using Rotating Magnetic Field and Metal Rods

In recent years, redox reactions have harnessed light or mechanical energy to enable the formation of chemical bonds. We postulated a complementary approach that electromagnetic induction could promote the redox reaction of organic molecules using a rotating magnetic field and metal rods. Here, we r...

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Published inJournal of the American Chemical Society Vol. 146; no. 26; pp. 18143 - 18150
Main Authors Liu, Haodong, Han, Xuliang, Feng, Xiaomei, Zhang, Lizhi, Sun, Fenggang, Jia, Fuchao, Zhao, Zengdian, Liu, Hui, Li, Xinjin
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 03.07.2024
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Summary:In recent years, redox reactions have harnessed light or mechanical energy to enable the formation of chemical bonds. We postulated a complementary approach that electromagnetic induction could promote the redox reaction of organic molecules using a rotating magnetic field and metal rods. Here, we report that electromotive force activates the redox-active trifluoromethylating reagents. This magnetoredox system can be applied to the trifluoromethylation of heteroarenes with high regioselectivity and hydrotrifluoromethylation of alkenes without the need for catalysts and organic additives.
Bibliography:ObjectType-Article-1
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ISSN:0002-7863
1520-5126
1520-5126
DOI:10.1021/jacs.4c05987