Effect of Electrolyte Media on the Catalysis of Fe Phthalocyanine toward the Oxygen Reduction Reaction: Ab Initio Molecular Dynamics Simulations and Experimental Analyses
FeN4 macrocycles are among the most promising nonprecious metal catalysts for the oxygen reduction reaction (ORR). Nevertheless, these catalysts perform poorly in acidic media. To understand what impedes the use of these catalysts in acid, graphite electrodes were drop-coated with inks of iron phtha...
Saved in:
Published in | ACS catalysis Vol. 12; no. 20; pp. 12786 - 12799 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
21.10.2022
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | FeN4 macrocycles are among the most promising nonprecious metal catalysts for the oxygen reduction reaction (ORR). Nevertheless, these catalysts perform poorly in acidic media. To understand what impedes the use of these catalysts in acid, graphite electrodes were drop-coated with inks of iron phthalocyanine adsorbed on carbon nanotubes (FePc-CNTs), and the electrocatalytic behavior of the catalyst was studied in four different supporting electrolytes (i.e., HCl, H2SO4, CH3COOH, and NaOH) by means of cyclic voltammetry, polarization curves, and electrochemical impedance spectroscopy. Electrolyte media are theoretically analyzed by ab initio molecular dynamic simulations, with explicit water molecules, to explain and visualize the occurring physical adsorption phenomena. The demetallation of the catalyst could be excluded because more than 3.6 eV would be necessary for this process to occur. In addition, the absorption of the anion of the specific acids at the Fe center was found to compete with the coordination of oxygen and prevent the catalytic process, modifying the ORR rate-determining step and the final product of the reaction. An electrochemical analysis and impedance spectroscopy corroborate this process. |
---|---|
ISSN: | 2155-5435 2155-5435 |
DOI: | 10.1021/acscatal.2c03298 |