Doubly Interpenetrated Metal–Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature
A doubly interpenetrated metal–organic framework [Cu2L(DMF)(H2O)]·DMF·H2O (ZJU-199, ZJU = Zhejiang University; H3BTTA = benzene-1,3,5-triacrytic acid; DMF = N,N-dimethylformamide) has been successfully synthesized. The resulting ZJU-199 exhibits moderate C2H2 uptake of 128.0 cm3·g–1 and high selec...
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Published in | Crystal growth & design Vol. 16; no. 12; pp. 7194 - 7197 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
07.12.2016
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Online Access | Get full text |
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Summary: | A doubly interpenetrated metal–organic framework [Cu2L(DMF)(H2O)]·DMF·H2O (ZJU-199, ZJU = Zhejiang University; H3BTTA = benzene-1,3,5-triacrytic acid; DMF = N,N-dimethylformamide) has been successfully synthesized. The resulting ZJU-199 exhibits moderate C2H2 uptake of 128.0 cm3·g–1 and high selectivity for separation of C2H2/CH4 (27.3 to 33.5) and C2H2/CO2 (4.0 to 5.8) at room temperature. |
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ISSN: | 1528-7483 1528-7505 |
DOI: | 10.1021/acs.cgd.6b01382 |