Doubly Interpenetrated Metal–Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature

A doubly interpenetrated metal–organic framework [Cu2L­(DMF)­(H2O)]·DMF·H2O (ZJU-199, ZJU = Zhejiang University; H3BTTA = benzene-1,3,5-triacrytic acid; DMF = N,N-dimethylformamide) has been successfully synthesized. The resulting ZJU-199 exhibits moderate C2H2 uptake of 128.0 cm3·g–1 and high selec...

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Published inCrystal growth & design Vol. 16; no. 12; pp. 7194 - 7197
Main Authors Zhang, Ling, Zou, Chao, Zhao, Min, Jiang, Ke, Lin, Ruibiao, He, Yabing, Wu, Chuan-De, Cui, Yuanjing, Chen, Banglin, Qian, Guodong
Format Journal Article
LanguageEnglish
Published American Chemical Society 07.12.2016
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Summary:A doubly interpenetrated metal–organic framework [Cu2L­(DMF)­(H2O)]·DMF·H2O (ZJU-199, ZJU = Zhejiang University; H3BTTA = benzene-1,3,5-triacrytic acid; DMF = N,N-dimethylformamide) has been successfully synthesized. The resulting ZJU-199 exhibits moderate C2H2 uptake of 128.0 cm3·g–1 and high selectivity for separation of C2H2/CH4 (27.3 to 33.5) and C2H2/CO2 (4.0 to 5.8) at room temperature.
ISSN:1528-7483
1528-7505
DOI:10.1021/acs.cgd.6b01382