One-Pot Synthesis of a New Magnetically Coupled Heterometallic Cu2Mn2 [2 × 2] Molecular Grid

The heterometallic [2 × 2] grid-type complex [Cu2Mn2(pop)4(OAc)4]·7H2O (1) has been selectively synthesized in a targeted one-pot reaction. Single-crystal X-ray analysis shows the expected structure with identical metal ions located at diagonal vertices of the grid. Magnetochemical studies reveal th...

Full description

Saved in:
Bibliographic Details
Published inInorganic chemistry Vol. 49; no. 11; pp. 4750 - 4752
Main Authors Moroz, Yurii S, Szyrwiel, Łukasz, Demeshko, Serhiy, Kozłowski, Henryk, Meyer, Franc, Fritsky, Igor O
Format Journal Article
LanguageEnglish
Japanese
Published American Chemical Society 07.06.2010
Online AccessGet full text

Cover

More Information
Summary:The heterometallic [2 × 2] grid-type complex [Cu2Mn2(pop)4(OAc)4]·7H2O (1) has been selectively synthesized in a targeted one-pot reaction. Single-crystal X-ray analysis shows the expected structure with identical metal ions located at diagonal vertices of the grid. Magnetochemical studies reveal that 1 has a ferrimagnetic spin ground state with some admixture of low-lying excited states.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic100555s