Unidirectional Energy Transfer in Conjugated Molecules: The Crucial Role of High-Frequency CC Bonds
Excited-state nonadiabatic molecular dynamics is used to study energy transfer in dendrimer building blocks, between two-, three-, and four-ring linear polyphenylene ethynylene units linked by meta-substitutions. Upon excitation, dendrimers with these building blocks have been shown to undergo highl...
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Published in | The journal of physical chemistry letters Vol. 1; no. 18; pp. 2699 - 2704 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
16.09.2010
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Subjects | |
Online Access | Get full text |
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Summary: | Excited-state nonadiabatic molecular dynamics is used to study energy transfer in dendrimer building blocks, between two-, three-, and four-ring linear polyphenylene ethynylene units linked by meta-substitutions. Upon excitation, dendrimers with these building blocks have been shown to undergo highly efficient and unidirectional energy transfer. The simulations start by initial vertical excitation to the S4, localized on the two-ring unit. We observe ultrafast directional S4 → S3 → S2 → S1 electronic energy transfer, corresponding to sequential two-ring → three-ring → four-ring transfer. The electronic energy transfer is concomitant with vibrational energy transfer through a dominant CC stretching motion. Upon S n+1 → S n population transfer, a rapid increase of the S n+1−S n energy gaps and decrease of the corresponding values for S n −S n−1 gaps are observed. As a consequence, the S n+1 and S n states become less coupled, while the S n and S n−1 become more coupled. This behavior guarantees the successful S n+1 → S n → S n−1 unidirectional energy transfer associated with the efficient energy funneling in light-harvesting dendrimers. |
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ISSN: | 1948-7185 1948-7185 |
DOI: | 10.1021/jz100794z |