Solvent-Soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2– Unit

A new 2D coordination polymer consisting of CuII ions, bis-imidazole-type ligands, and CO3 2– was prepared. This compound converted to new pentanuclear complexes with cyclic frameworks, which trapped a kinetically labile [Cu(CO3)2]2– unit, by recrystallization from MeOH/Et2O or EtOH/Et2O.

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Bibliographic Details
Published inInorganic chemistry Vol. 52; no. 9; pp. 4765 - 4767
Main Authors Inoue, Tatsunari, Yamanishi, Katsunori, Kondo, Mitsuru
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 06.05.2013
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Summary:A new 2D coordination polymer consisting of CuII ions, bis-imidazole-type ligands, and CO3 2– was prepared. This compound converted to new pentanuclear complexes with cyclic frameworks, which trapped a kinetically labile [Cu(CO3)2]2– unit, by recrystallization from MeOH/Et2O or EtOH/Et2O.
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic400315g