High-Performance Pr3+-Doped Scandate Optical Thermometry: 200 K of Sensing Range with Relative Temperature Sensitivity above 2%·K–1

• Published in: ACS applied materials & interfaces Vol. 11; no. 45; pp. 42330 - 42338
• Main Authors: Wang, Shuxian, Ma, Shuwei, Zhang, Guanggang, Ye, Zhengmao, Cheng, Xin
• Format: Journal Article
• Language: English
• Published: American Chemical Society 13.11.2019
• Subjects: sensing range; fluorescence intensity ratio; fluorescence thermometry; Pr3+ ions; relative temperature sensitivity
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.9b13873

Nowadays, for lanthanide fluorescence thermometry, high relative temperature sensitivity (S r) and wide sensing range are urgently required in practical applications. Herein, a Pr3+-doped scandate (Pr3+:CaSc2O4) luminescent thermometer is proposed, and the related crystal-field splitting of Pr3+ ions is systematically discussed. The 4f5d-4f and 4f-4f emissions of Pr3+ ions in CaSc2O4 basically present positive and negative correlation relationships with the increase in temperature, respectively. The different changing tendencies in relation to temperature for the two kinds of transitions are mainly derived from the effects of the thermally activated trap energy levels and the crossover process between 5d and 4f energy states of Pr3+ ions and are beneficial for the enhancement of relevant temperature sensitivities. The obtained experimental results manifest that Pr3+:CaSc2O4 owns a maximum relative temperature sensitivity S r of 2.49%·K–1 (at 390 K) and a low temperature uncertainty (around 0.1 K from 275 to 490 K). Moreover, it is also able to keep a relatively high S r (not lower than 2%·K–1) over a wide temperature sensing range (∼200 K), which is more excellent than those of reported luminescent thermometric materials (∼100 K). Hence, what discussed in this study might provide a useful design perspective for the exploration and development of high-performance luminescent thermometers with a wide applicable temperature range.