Size Effects Observed via the Electrical Response of BaTiO3 Nanoparticles in a Cavity

• Published in: Journal of physical chemistry. C Vol. 116; no. 44; pp. 23742 - 23748
• Main Authors: Lomax, Joseph F, Fontanella, John J, Edmondson, Charles A, Wintersgill, Mary C, Westgate, Mark A, Eker, Sitki
• Format: Journal Article
• Language: English
• Published: Columbus, OH American Chemical Society 08.11.2012
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Dielectric loss and relaxation; Dielectric properties of solids and liquids; Dielectrics, piezoelectrics, and ferroelectrics and their properties; Exact sciences and technology; Physics; Nanoparticles; Particle size; Barium Zirconates; Phase transformations; Temperature effects; Dielectric losses; Size effect; Arrhenius equation; Perovskites; Barium titanates; Dielectric relaxation
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/jp307218v

Barium titanate (BaTiO3) is one of the most widely used electronic materials. The origin of changing structural and electronic behavior between larger and smaller nanoparticles in BaTiO3 has been extensively investigated. Here, the dielectric loss measured for BaTiO3 or BaZrO3 particles in a cavity at audio frequencies (10–105 Hz) and low temperatures (5.5–350 K) is reported. Distinct differences were found between small (50–100 nm diameter/cubic) and large (>200 nm diameter/tetragonal at room temperature) BaTiO3 particles. Isochronal relaxation features observed around 20 K showed differing shape and dynamics (50–100 nm particles: broad peak, E act ≈ 0.04 eV, log10(f pre(s)) ≈ 14.7; >200 nm particles: sharp peak, E act ≈ 0.025 eV and log10(f pre(s)) ≈ 12, with a shoulder). The low-temperature relaxations are attributed to the motion of off-center titanium ions. In support of this identification, low-temperature relaxations were not observed in BaZrO3 nanoparticles. Finally, structural change features were observed at about 180 and 270 K in the larger BaTiO3 particles (rhombohedral at low temperature) but not in the smaller particles (cubic at all temperatures). The results provide a new set of testable bounds that should contribute to the understanding of nanoparticle-sized BaTiO3, in particular, and ferroelectric behavior in perovskites, in general.