Synthesis and Characterization of Starlike Complexes Containing Three Terminal Butterfly Fe/S Cluster Cores Generated via Reactions of the Three-μ-CO-Containing Trianions {[(μ-CO)Fe2(CO)6]3[(μ-SCH2CH2)3N]}3- and {[(μ-CO)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3- with Electrophiles
The novel three-μ-CO-containing trianions {[(μ-CO)Fe2(CO)6]3[(μ-SCH2 CH2)3N]}3- (4A) and {[(μ-CO)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3- (4B) were prepared by reaction of trithiol N(CH2CH2SH)3 or 1,3,5-(HSCH2)3C6H3 with Fe3(CO)12 and Et3N in 1:3:3 molar ratio in THF at room temperature. Further in situ t...
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Published in | Organometallics Vol. 24; no. 15; pp. 3764 - 3771 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
18.07.2005
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Online Access | Get full text |
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Summary: | The novel three-μ-CO-containing trianions {[(μ-CO)Fe2(CO)6]3[(μ-SCH2 CH2)3N]}3- (4A) and {[(μ-CO)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3- (4B) were prepared by reaction of trithiol N(CH2CH2SH)3 or 1,3,5-(HSCH2)3C6H3 with Fe3(CO)12 and Et3N in 1:3:3 molar ratio in THF at room temperature. Further in situ treatment of 4A with electrophiles Ph2PCl, PhSBr, PhC(Cl)NPh, and CH2CHCH2Br afforded starlike complexes [(μ-Y)Fe2(CO)6]3[(μ-SCH2CH2)3N] (5−8: Y = Ph2P, PhS, PhCNPh, CH2CHCH2), whereas its reaction with CS2 followed by treatment with organic halides RX produced complexes [(μ-Y)Fe2(CO)6]3[(μ-SCH2CH2)3N] (9−11: Y = MeSCS, PhCH2SCS, CH2CHCH2SCS). Similarly, 4B reacted in situ with Ph2PCl, PhSBr, PhC(Cl)NPh, CH2CHCH2Br, and PhNCS to give starlike complexes [(μ-Y)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3] (12−16: Y = Ph2P, PhS, PhCNPh, CH2CHCH2, PhNHCS), whereas its reaction with CS2 followed by treatment with RX yielded complexes [(μ-Y)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3] (17−19: Y = MeSCS, PhCH2SCS, CH2CHCH2SCS). All the starlike complexes 5−19 contain three terminal butterfly Fe/S cluster cores, which have been fully characterized by elemental analysis and spectroscopy, and particularly by X-ray diffraction techniques for 5, 12, 15, and 17. |
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Bibliography: | istex:EF34A6893686D780ACBF646C08EB79A754746BDE ark:/67375/TPS-SDMSQPTC-H |
ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om050333a |