Mechanism and Stereochemistry of the Reaction of Dichloroplatinum(II) Complexes with Diazo Compounds. X-ray Structures of Four Key Products:  [(2R,3R)-Bis(diphenylphosphino)butane]chloro- [(S)-chloro(methoxycarbonyl)methyl]platinum(II), (η4-1,5-Cyclooctadiene)[3-chloro-5-(dimethoxyphosphonyl)-2- methoxy-4,1,2-platinaoxaphospholane P-oxide], (R,R)-[Chloro(dimethoxyphosphonyl)methyl][chloro- (trimethylsilyl)methyl](1,5-cyclooctadiene)platinum(II), and Chloro[chloro(dimethoxyphosphonyl)methyl](η4-1

The structures of four key products formed by reaction of diazo compounds of the type RCHN2 (R = CO2Me, P(O)(OMe)2, SiMe3) with chloroplatinum(II) derivatives have been elucidated by X-ray crystallographic methods. The results confirm our earlier conclusions, based on NMR evidence and mechanistic co...

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Published inOrganometallics Vol. 16; no. 5; pp. 1053 - 1057
Main Authors Ferguson, George, Gallagher, John F, McAlees, Alan J, McCrindle, Robert
Format Journal Article
LanguageEnglish
Published American Chemical Society 04.03.1997
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Summary:The structures of four key products formed by reaction of diazo compounds of the type RCHN2 (R = CO2Me, P(O)(OMe)2, SiMe3) with chloroplatinum(II) derivatives have been elucidated by X-ray crystallographic methods. The results confirm our earlier conclusions, based on NMR evidence and mechanistic considerations, concerning the stereochemistries of these products.
Bibliography:istex:E8C64760D9F978858F21439ED4E3321D5E9CED71
ark:/67375/TPS-S1NJ6BP4-6
Abstract published in Advance ACS Abstracts, February 1, 1997.
ISSN:0276-7333
1520-6041
DOI:10.1021/om9607964