Reactions of the Three-μ-CO-Containing Trianions {[Fe2(μ-CO)(CO)6]3[(μ-SCH2CH2)3N]}3- and {[Fe2(μ-CO)(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3- To Give Starlike Complexes Terminated with Butterfly Fe/S Cluster Cores
Five starlike complexes with terminal butterfly Fe/S cluster cores, [Fe2(μ-Ph2P)(CO)6]3[(μ-SCH2CH2)3N] (2), [Fe2(μ-PhS)(CO)6]3[(μ-SCH2CH2)3N] (3), [Fe2(μ-PhCNPh)(CO)6)]3[1,3,5-(μ-SCH2)3C6H3] (5), and [Fe2(μ-RSCS)(CO)6]3[1,3,5-(μ-SCH2)3 C6H3] (7, R = Me; 8, R = PhCH2), were prepared by a “one pot”...
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Published in | Organometallics Vol. 24; no. 4; pp. 472 - 474 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
14.02.2005
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Online Access | Get full text |
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Summary: | Five starlike complexes with terminal butterfly Fe/S cluster cores, [Fe2(μ-Ph2P)(CO)6]3[(μ-SCH2CH2)3N] (2), [Fe2(μ-PhS)(CO)6]3[(μ-SCH2CH2)3N] (3), [Fe2(μ-PhCNPh)(CO)6)]3[1,3,5-(μ-SCH2)3C6H3] (5), and [Fe2(μ-RSCS)(CO)6]3[1,3,5-(μ-SCH2)3 C6H3] (7, R = Me; 8, R = PhCH2), were prepared by a “one pot” reaction of the trithiol N(CH2CH2SH)3 or 1,3,5-(HSCH2)3C6H3 with Fe3(CO)12 and Et3N, followed by treatment of the intermediate three-μ-CO-containing trianions {[Fe2(μ-CO)(CO)6]3[(μ-SCH2CH2)3N]}3- (1) and {[Fe2(μ-CO)(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3- (4) with Ph2PCl, PhSBr, PhC(Cl)NPh, CS2/MeI, and CS2/PhCH2Br, respectively. These products have been fully characterized by elemental analysis, spectroscopy, and X-ray crystallography. |
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Bibliography: | ark:/67375/TPS-5FLW859Z-1 istex:60A03A270688B98022CA06B2DDD50CEAFE44A22A |
ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om0490280 |