Fast Room-Temperature Mg2+ Conductivity in Mg(BH4)2·1.6NH3–Al2O3 Nanocomposites

• Published in: The journal of physical chemistry letters Vol. 13; no. 9; pp. 2211 - 2216
• Main Authors: Yan, Yigang, Grinderslev, Jakob B, Burankova, Tatsiana, Wei, Shanghai, Embs, Jan P, Skibsted, Jørgen, Jensen, Torben R
• Format: Journal Article
• Language: English
• Published: American Chemical Society 10.03.2022
• Subjects: Physical Insights into Energy Science
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.2c00136

Design of new functional materials with fast Mg-ion mobility is crucial for the development of competitive solid-state magnesium batteries. Herein, we present new nanocomposites, Mg­(BH4)2·1.6NH3–Al2O3, reaching a high magnesium conductivity of σ­(Mg2+) = 2.5 × 10–5 S cm–1 at 22 °C assigned to favorable interfaces between amorphous state Mg­(BH4)2·1.6NH3; inert and insulating Al2O3 nanoparticles; and a minor fraction of crystalline material, mainly Mg­(BH4)2·2NH3. Furthermore, quasi-elastic neutron scattering reveals that the Mg2+-ion mobility in the solid state appears to be correlated to relatively slow motion of NH3 molecules rather than the fast dynamics of BH4 – complexes. The nanocomposite is compatible with a metallic Mg anode and shows stable Mg2+ stripping/plating in a symmetric cell and an electrochemical stability of ∼1.2 V. The nanocomposite has high mechanical stability and ductility and is a promising Mg2+ electrolyte for future solid-state magnesium batteries.