Ab Initio Site Occupancy and Far-Red Emission of Mn4+ in Cubic-Phase La(MgTi)1/2O3 for Plant Cultivation

• Published in: ACS applied materials & interfaces Vol. 9; no. 7; pp. 6177 - 6185
• Main Authors: Zhou, Ziwei, Zheng, Jiming, Shi, Rui, Zhang, Niumiao, Chen, Jiayu, Zhang, Ruoyu, Suo, Hao, Goldys, Ewa M, Guo, Chongfeng
• Format: Journal Article
• Language: English
• Published: American Chemical Society 22.02.2017
• Subjects: plant growth; phytochrome; phosphor; far-red emission; LEDs
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.6b15866

Mn4+-activated oxide phosphors La­(MgTi)1/2O3 (LMT) with far-red emitting were prepared via a sol–gel route. The structures of samples were determined by X-ray diffraction (XRD) and Reitveld refinement. The occupied sites of Mn4+ (d 3 electronic configuration) in host La­(MgTi)1/2O3 were confirmed by ab initio calculations in which the system has the lower formation energy, stable lattice structure, and strong bonding state as Mn4+ enters into Ti site. The luminescent properties of Mn4+-doped samples were investigated; the samples emit far-red light centered at 708 nm with ultraviolet light (345 nm) or blue light (487 nm) excitation. According to the photoluminescence (PL) and excitation (PLE) spectra, the crystal field strength of the Mn4+-occupied environment was estimated. The thermal stability of phosphor was also evaluated through temperature-dependent PL intensity in a heating and cooling cycle process. The emission band is well-matched with the absorption band of phytochrome P FR under the excitation of light in near-ultraviolet to blue, which suggests that the LMT: Mn4+ phosphor has great potential applications in light-emitting diodes (LEDs) for modulating plant growth.