A Tetrahedral Water Tetramer in a Zeolite-like Metal−Organic Framework Constructed from {(H3O)2[Fe6O{(OCH2)3CCH3}4Cl6]·4H2O}

For the first time, a tetrahedral water tetramer was observed in a zeolite-like metal−organic framework constructed from {(H3O)2[Fe6O{(OCH2)3CCH3}4Cl6]·4H2O}, in which the host plays an important role in stabilization of this unstable species predicted by theoretical calculations.

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Bibliographic Details
Published inCrystal growth & design Vol. 6; no. 6; pp. 1264 - 1266
Main Authors Jiang, Guoqing, Bai, Junfeng, Xing, Hang, Li, Yizhi, You, Xiaozeng
Format Journal Article
LanguageEnglish
Published Washington,DC American Chemical Society 07.06.2006
Subjects
Chemistry
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
General and physical chemistry
Ion-exchange
Organic compounds
Organometalloidal and organometallic compounds
Physics
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Surface physical chemistry
Iron oxide
Stacking sequence
Stabilization
Tetramer
Organometallic compound
Zeolite
Experimental study
Fill factor
Single crystal
Hydrogen bond
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Summary:For the first time, a tetrahedral water tetramer was observed in a zeolite-like metal−organic framework constructed from {(H3O)2[Fe6O{(OCH2)3CCH3}4Cl6]·4H2O}, in which the host plays an important role in stabilization of this unstable species predicted by theoretical calculations.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg0600389