Multifunctional Anionic MOF Material for Dye Enrichment and Selective Sorption of C2 Hydrocarbons over Methane via Ag+‑Exchange

The anionic Zn-2,5-thiophene­dicarboxylate framework material (1) built from the connection of Johnson cages can perform Ag+-exchange to upgrade the uptakes of C2 hydrocarbons (C2s) and separation properties of C2s over methane (C1). Moreover, its activated phase (1a) can enrich organic dyes from et...

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Bibliographic Details
Published inInorganic chemistry Vol. 53; no. 24; pp. 12973 - 12976
Main Authors Tan, Yan-Xi, Zhang, Ying, He, Yan-Ping, Zheng, Yan-Jun, Zhang, Jian
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 15.12.2014
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Summary:The anionic Zn-2,5-thiophene­dicarboxylate framework material (1) built from the connection of Johnson cages can perform Ag+-exchange to upgrade the uptakes of C2 hydrocarbons (C2s) and separation properties of C2s over methane (C1). Moreover, its activated phase (1a) can enrich organic dyes from ethanol and make a significant red-shift in photoluminescent spectra of Rhodamine B (Rh B) via varying the aggregation states of dye molecules.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic5020829