Binary- and Pure-Component Adsorption of CO2, H2O, and C6H14 on SSZ-13

• Published in: Industrial & engineering chemistry research Vol. 59; no. 40; pp. 18151 - 18159
• Main Authors: Thompson, Joshua A, Zones, Stacey I
• Format: Journal Article
• Language: English
• Published: American Chemical Society 07.10.2020
• Subjects: Separations
• ISSN: 0888-5885; 1520-5045
• DOI: 10.1021/acs.iecr.0c03480

Adsorption isotherms on Na-SSZ-13, a small-pore zeolite, for pure-component adsorbates CO2, H2O, and C6H14 were measured using a gravimetric adsorption instrument with a temperature range between 30 and 100 °C. These isotherm data were fit to a multisite Langmuir adsorption model. Using the same gravimetric adsorption instrument, binary adsorption isotherms for the adsorbate pairs CO2–H2O and CO2–C6H14 were measured with a temperature range between 30 and 80 °C. These data demonstrated that the increasing loading of either H2O or C6H14 impacted the loading of CO2 on Na-SSZ-13. The binary isotherm data were compared with ideal adsorbed solution theory and showed relatively good agreement between the data and modeling.